Have you ever cooked something - like, a minestrone soup or a curry with a lot of vinegar - and noticed that the vegetables stay firm and hard even after long cooking? It's not the vegetables or your cooking skills, it's the amount of acidic liquids in the cooking liquid!
As you've no doubt observed in your everyday cooking, vegetables normally soften as they cook. A big part of this is because cells in the vegetable are held together with a particular kind of carbohydrate called hemicelluloses (say that five times fast!). These hemicelluloses dissolve in the heat and steam of cooking, weakening the cell walls and causing the vegetables to soften.
But here's the deal - hemicelluloses aren't soluble in acid and therefore won't dissolve if the cooking environment is too acidic. So once you've added the tomatoes to a minestrone or the vinegar to a sauce, vegetables essentially stop cooking exactly where they are.
The simple solution to this is to add the acidic component toward the very end of cooking. You can also cook vegetables separately until they're as soft as you want them and then add them to the main pot.
And look on the bright side, at least you'll never get mushy vegetables!
Have you ever noticed this phenomenon happening in any of your recipes?
Related: Food Science: Why Sliced Fruit Turns Brown
(Image: Flickr member yoppy licensed under Creative Commons)

Comments (11)
Wow, what a timely post! I just made minestrone for the first time the other night and the carrots would not soften! I'm glad to know it was because of the tomatoes. I'll definitely remember to add them towards the end next time :) Thanks!
Couldn't figure it out, the potatoes in my minestrone were hard as rocks but everything else was just fine. I think I'll cook them seperately next time.
This explains the carrots in my last beef stew.
This happens to beans as well - Rancho Gordo's website advises leaving tomatoes out of the cooking until the end.
I made the borlotti beans with polenta recipe and could not figure out why the fennel would not soften after 2 hours of cooking. This explains it.
Brilliant! I love a really lemony chicken soup, so next time I'll add the lemon earlier and not have mushy veg for a change... hooray!
I made the poached celery in Mastering the Art of French Cooking last fall. I cooked it for some incredible amount of time - 45 minutes, perhaps - and it was inedible. Actually, one brave dinner party guest claimed to love it and used a steak knife to cut it into bite sized pieces...
interesting AND useful! :)
Ohmigosh!!! So helpful. Thanks!
Hmm, that would probably explain all of my rock hard carrots in everything. Great post!
That is such a handy thing to have in the back of my mind-sometimes I don't know why recipes tell you to add things in a certain order (I'm a bung-it-all-in kind of person!) but if there's a good reason then I will do it! I have experienced the hard carrot phenonemon.